Yikes. What a terrible idea to place your brand's reputation in the hands of people that don't hesitate to make assumptions about your customers' intelligence. Adobe allows certain users to speak as "Pros" on their help boards based on their past helpfulness, which has gotten out of hand before, but they certainly make the distinction between staff and user in the nameplate so people know not to associate them with the company itself.
Is the point of volunteering to put it on your résumé for future employment opportunities in customer service?
Wait, what? Volunteering in general or even open source or community software projects makes plenty of sense, but why the hell would anyone volunteer for a private for-profit like Dropbox?
For all intents and purposes, they represent Dropbox. It is poor choice of Dropbox to let themselves be represented by unqualified, unvetted people and then distance themselves from it "because they are not getting paid". They work for Dropbox, they just do it for free.